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Since the mid-1950s when Ziegler Natta catalysts that yielded high-molecularweight resin were discovered, the demand for polypropylene has increased dramatically The conventional catalyst systems used in its manufacture are quite versatile and can be adapted to produce the homopolymer, block copolymers, and random copolymers with other monomers With increased production, polypropylene has become cost effective to a point where it could be used in a variety of low-value packaging applications such as containers, closures, biaxially oriented lm, and tape The United States presently accounts for about 25% of the global production capacity of the resin The recently developed metallocene catalysts have been used for the polymerization of propylene as well This novel route allows close control of the degree of stereoregularity of the resin and the copolymerization of the propylene with a much wider selection of co-monomers (compared to conventional catalyst systems).
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PDF, as a PDF component allows its users to not only to convert images of commonly used formats to PDF document such as jpg, bmp, png, but also to convert ...
I started as fundraising director for Greenpeace Argentina in 1995. Argentina was then an almost virgin market in professional fundraising, with all the advantages, challenges, and inconveniences that a new market presents. Instead of copying the established models, we ran multiple tests to find out which was the most appropriate form of media for Greenpeace Argentina. We incorporated integration of online media in 1996. We had our first donor through our Web page www.greenpeace.org.ar in the same year. Our Web site has subsequently transformed itself into a response channel whereby a third of new donors join Greenpeace Argentina (see Exhibit 3.1). The Greenpeace Argentina case began to be published and presented in the main international conferences, without our seeking this out, because of the diverse and successful strategies we have been working with since the middle of the 1990s. Following Jules Verne s thought that by knowing your village you will know the world, we systemized the general teachings of the Seven Elastic Rules of Online Fundraising : 1. Change organizational culture, or how to make bytes an integral part of your existence. 2. Use the Web site as a response channel. 3. Develop a strong e-mail fundraising program.
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Metallocene grades of polypropylene (mPP), including syndiotactic resins, are already available commercially but still constitute only a small fraction of the total production Polypropylene is typically manufactured by the direct polymerization of propylene in a low-pressure process employing Ziegler Natta catalyst systems (typically aluminum alkyls and titanium halides with optional ether, ester, or silane activators) The process can be carried out in liquid or slurry in conventional manufacturing or in the newer gas-phase stirred-bed or uidized-bed reactors The polymerization generally yields an isotactic index (generally measured as the percent insolubles in heptane) of 85 99 The isotactic form of the polymer with a high degree of crystallinity (40 60%) is preferred for most practical applications Isotactic polypropylene (iPP), the principal type used by the polymer processing industry, has a density of about 092 094 g/cm3 .
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The weight-average molecular weight of polypropylene from these processes is in the range of 300,000 600,000 with a polydispersity index of about 2 6 [13] Some atactic polypropylene results as a by-product9 of the process and has found limited practical use [14] The atactic form is mostly amorphous and has a density of only about 085 090 g/cm3 Small amounts of the syndiotactic form of polypropylene (where the methyl groups on repeat units are located on alternate sides of the chain on adjacent.
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